Investigators search for the cause of a fire that killed several people in Sadie and David Proffitt's Florida apartment complex.

Deadly Wives

Murder for Proffitt

Wives that are polar opposites of their partners; a popular woman marries a shy engineer, but their marriage is cut short when he is killed; a woman goes missing.

Opposites Attract

After she falls in love with another man, Catherina Voss takes drastic measures to end her marriage; Barbara Cipriano becomes a suspect when her husband is found dead.

The Liars Club

Police discover that Cristie Sehome is the keeper of fatal family secrets; detectives unravel the truth behind the deaths of Raynella Leath's two husbands.

Where There's a Will, There's a Way

Police look into Lynn Stomps' story when her husband disappears; Bill McGuire disappears following an argument with his wife, Melanie.

Vanishing Acts

In Edgewood, Kentucky, Stephen and Adele Craven have been together for more than a decade; Stephen is frequently away for work and Adele has a lover on the side; when Stephen turns up dead, investigators are faced with a puzzling crime scene.

Craven for Murder

Two stories of deadly wives exchanging love for lust and greed.

Pretty Young Deadly Things

A husband disappears as his marriage edges toward divorce.

Acid Lady

Sacramento, Calif., attorney Larry McNabney lives the high life with his wife, Elisa, until his sudden disappearance.

Marlboro Man Murder

A North Carolina woman leads a double life; an elderly husband winds up dead after his wife takes him to a swimming pool.

Things Aren't Always What They Seem

Real-life stories of women who murder their husbands.

S1 E4 | Acid Lady